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91.
C. T. Vijayakumar E. Ponnusamy T. Balakrishnan H. Kothandaraman 《Journal of polymer science. Part A, Polymer chemistry》1982,20(9):2715-2725
Random copolyesters of dimethyl terephthalate (DMT), ethylene glycol (EG), and butane-1,4-diol (BD) and the homopolyesters poly(ethylene terephthalate) (PET) and poly(butylene terephthalate) (PBT) have been subjected to degradation and pyrolysis studies. Differential thermal analysis (DTA) showed that the decomposition temperature is dependent on the percentage of EG and BD present in the copolyesters. Thermal volatilization analysis (TVA) also showed that the decomposition temperature is dependent on the percentage of EG and BD present in the copolyesters. The trend for the decomposition temperatures obtained from TVA studies for these copolyesters is similar to such other thermal properties as melting temperature Tm, ΔHf, ΔHc, etc. The subambient thermal volatilization analysis (SATVA) curves obtained for these polymers are also presented. The SATVA curve is the fingerprint of the total volatile products formed during the degradation in high vacuum. The isothermal pyrolysis of these materials was carried out in high vacuum at 450°C. The products formed were separated in a gas chromatograph and were subsequently identified in a mass spectrometer. The major pyrolysis products from PBT were butadiene and tetrahydrofuran, whereas those from PET were ethylene and acetaldehyde. The ratio of acetaldehyde to ethylene increases with the EG content in the copolyester, suggesting a different decomposition mechanism compared to the decomposition mechanism of PBT and PET. 相似文献
92.
The isomerisation of acetates from the Baylis-Hillman adducts with Mont.K10 clay-microwave combination furnished E-trisubstituted alkenes in high yield. The simple Baylis-Hillman adducts with trimethyl orthoformate and unsaturated alcohols under clay catalytic condition gave densely functionalised-isomerized products under solvent free condition. Application of the propargyl derivatives thus obtained from the isomerisation of the Baylis-Hillman adducts with propargyl alcohol has been demonstrated in the synthesis of lignan core structures by tri-n-butyltin hydride mediated vinyl radical cyclization. 相似文献
93.
Kell AJ Somaskandan K Stewart G Bergeron MG Simard B 《Langmuir : the ACS journal of surfaces and colloids》2008,24(7):3493-3502
There is currently significant interest in the miniaturization of disease detection platforms. As detection platforms decrease in size there is a need for the development of sample preparation protocols by which cells or biomarkers of interest can be concentrated from large volumes down to volumes more amenable to analysis within microfluidic devices. To address this issue, we present a series of magnetic confinement assays for polystyrene (PS) beads mediated through their covalent modification with a series of superparamagnetic nanoparticles, where the PS beads have many properties similar to bacteria, but are not pathogenic. The magnetic confinement of the PS beads is investigated as a function of (1) the overall nanoparticle size, (2) the loading of superparamagnetic content within the nanoparticle matrix, and (3) the viscosity and volume of the dispersion medium. We demonstrate that the time required for the magnetic capture of the PS beads by the superparamagnetic nanoparticles (1) decreases as the loading of superparamagnetic material into the nanoparticles increases and (2) increases as the viscosity and volume of the dispersion medium are increased. However, limitations in the magnetic confinement efficiency for the PS beads labeled with nanoparticles comprised of low loadings of superparamagnetic material can be overcome through the use of magnetic columns. These magnetic columns provide a practical and fast mode of sample preparation that should facilitate the magnetic concentration of cells and biomarkers from large volumes to volumes more amenable to incorporation into a microfluidic-based analysis system, where they can be analyzed/detected. 相似文献
94.
Kandapalam Arun Prasath LingamAsit Baran Mandal Ponnusamy Shanmugam 《Tetrahedron letters》2011,52(28):3610-3613
A novel magnesium iodide mediated unusual dimerization-spirocyclopropanation of bromo isomerised Morita-Baylis-Hillman adducts of isatin afforded highly functionalized 3-spirocyclopropane-2-oxindole derivatives as regioisomers in good combined yield. It has been observed that the regioselectivity is dependent on the nature of electron withdrawing group at the activated position. A plausible mechanism involving organomagnesium reagent has been proposed. 相似文献
95.
J D. Bilavendran Alagumuthu Manikandan Ponnusamy Thangarasu K Sivakumar 《Journal of heterocyclic chemistry》2020,57(3):1143-1153
A family of 11 nitrophenol 2-nitro-5-(4-substituted phenylquinolin-2-yl)phenol derivatives (4, 4a-j) was effectively synthesized as antimicrobial medications. A mixture of the substituted 3-hydroxy-4-nitrobenzaldehyde substituted aromatic amine and substituted phenylacetylenes were used to synthesis the title compounds 4, 4a-j. Antimicrobialactivity potential of 4, 4a-j was evaluated against Streptococcus pyogenes (MTCC 442), Staphylococcus aureus (MTCC 96), Pseudomonas aeruginosa (MTCC 424), and Escherichia coli (MTCC 443). DNA gyrase inhibition studies carried out to understand the mechanism ofaction of the antimicrobial effect of target compounds. HRBC membrane stabilization (in vitro) property was also assessed as a representative human cellular cytotoxic effect of 4, 4a-j since HRBC alike lysosomal cells and the lysozyme activity leads to inflammation and its adverse effects in cellular systems. Results reveal that compounds 4c and 4h have remarkable antibacterial activity and screened for further preclinical studies. 相似文献
96.
97.
Ponnusamy Sami Natarajan Mariselvi Kandasamy Venkateshwari Murugesan Vairalakshmi Arunachalam Sarathi Kasi Rajasekaran 《Transition Metal Chemistry》2010,35(5):563-570
The kinetics of reduction of heteropoly 11-tungstovanadophosphate, [PVVW11O40]4−, (HPA1) and heteropoly 10-tungstodivanadophosphate, [PVVVVW10O40]5−, (HPA2) by thiourea has been investigated in HClO4/phthalate/acetate buffer solutions spectrophotometrically at 25 °C in aqueous medium. The stoichiometry of the reaction is
1:1 in both cases. The HPAs are converted into the corresponding one-electron reduced heteropoly blues, namely, [PVIVW11O40]5− and [PVIVVVW10O40]6−, and thiourea is oxidised to formamidine disulphide. The reaction shows first-order dependence in both [HPA] and [thiourea]
at constant pH. The rate–pH profile shows the participation of both the neutral and deprotonated forms of thiourea in the
reaction. The reaction proceeds through an outer sphere electron transfer mechanism in which activation-controlled electron
transfer is the rate-determining step. Self-exchange rate constants for the couples [PVVW11O40]4−/[PVIVW11O40]5−, [PVVVVW10O40]5−/[PVIVVVW10O40]6− and H2NCSNH2/H2NCS·+NH2 have been evaluated by Marcus theory. 相似文献
98.
Ming-Yuen Tsai Ponnusamy Vinoth Kumar Hong-Ping Li Jen-Fon Jen 《Journal of chromatography. A》2010,1217(12):1891-1897
A microwave-assisted headspace controlled-temperature liquid-phase microextraction (HS-CT-LPME) technique was applied for the one-step sample extraction of hexachlorocyclohexanes (HCHs) from aqueous samples with complicate matrices, followed by gas chromatographic (GC) analysis with electron capture detector (ECD). Microwave heating was applied to accelerate the evaporation of HCHs into the headspace and an external-cooling system was used to control the temperature in the sampling zone for HS-LPME. Parameters affecting extraction efficiency, such as LPME solvent, sampling position and temperature, microwave power and irradiation time (the same as sampling time), sample pH, and salt addition were thoroughly investigated. From experimental results, the following conditions were selected for the extraction of HCHs from 10-mL water sample (pH 2.0) by using 1-octanol as the LPME solvent, with sampling done at 38 °C for 6 min under 167 W of microwave irradiation. The detections were linear in the concentration of 0.1–10 μg/L for α-HCH and γ-HCH, and 1–100 μg/L for β-HCH and δ-HCH. Detection limits were 0.05, 0.4, 0.03 and 0.1 μg/L for α-, β-, γ- and δ-HCH, respectively. Environmental water samples were analyzed with recovery between 86.4% and 102.4% for farm-field water, and between 92.2% and 98.6% for river water. The proposed method proved to serve as a simple, rapid, sensitive, inexpensive, and eco-friendly procedure for the determination of HCHs in aqueous samples. 相似文献
99.
100.
Kinetic-spectrophotometric method for the determination of trace amounts of bromide in seawater 总被引:1,自引:0,他引:1
A novel simple, sensitive and rapid kinetic-spectrophotometric method is proposed for the determination of trace amounts of bromide. The method is based on its catalytic effect on the oxidation of methylene blue (MB) by hydrogen peroxide in strongly acidic solution. The oxidation reaction is activated by large amounts of chloride and can be monitored spectrophotometrically by measuring the decrease in the absorbance of MB at 746 nm. The determination of bromide is performed by a fixed-time method at the first 100 s from the initiation of the reaction. Unlike other kinetic-spectrophotometric methods for the determination of bromide, the proposed method does not require heating the solution. Bromide can be determined in the range from 80 to 960 μg l−1 with the detection limit of 35 μg l−1. The relative standard deviation of ten replicate determination of 480 μg l−1 bromide was 1.4%. The influence of potential interfering ions was studied. The proposed method was satisfactorily applied to the determination of bromide in seawater without interfering effect from chloride ion. 相似文献